![]() ![]() 3) Use the entropy values given to calculate ∆S o values for the following reaction: 2 CH 3 OH(g) + 3 O 2 (g) → 2 CO 2 (g) + 4 H 2 O(g) Compound ΔS° (J/mol∙K) CH 3 OH(g) 237. 2) Use the entropy values given to calculate ∆S o values for the following reaction: C 2 H 4 (g) + H 2 (g) → C 2 H 6 (g) Compound ΔS°(J/mol∙K) C 2 H 4 (g) 219. 2 PCl 3(g) + O2(g) Æ 2POCl 3(g) Student A calculated the ΔS for the reaction as follows: ΔS°reaction = − Student B calculated the ΔS for the reaction as follows: ΔS°reaction = − Did either student perform the calculation correctly? If not, what did they do wrong? If neither student performed the calculation correctly, what is the correct set-up and value for the entropy of the system? Compound ΔS°(J/mol∙K) PCl 3(g) 311. It may be interpreted as a measure of the dispersal or distribution of matter and/or energy in a system. 1 J/ mol∙K Y OU DO: 1) The entropy values for the reaction below are given in the table. Entropy ( S) is a state function that can be related to the number of microstates for a system (the number of ways the system can be arranged) and to the ratio of reversible heat to kelvin temperature. 4 □/□□□ ∙ □ Compound ΔS°(J/mol∙K) NH 3(g) 192. The absolute entropy of a substance at any temperature above 0 K must be determined by calculating the increments of heat q required to bring the substance from 0 K to the temperature of interest, and then summing the ratios q/T. If the reaction is: aA + bB Æ cC + dD then the entropy of the system would be calculated as, ΔS° reaction = − I DO: Use thermodynamic data to calculate ΔS° for the following reaction: 4 NH3(g) + 7 O 2(g) Æ 4 NO 2(g) + 6 H 2 O(g) ΔS° reaction = Σ∆S°products − Σ∆S°reactants ∆□°□□□ = − ∆□° □□□ = − 114. ΔS° reaction = Σ∆S° products − Σ∆S° reactants The values for the standard entropies can be found in the back of your text book or here. 15.2 Standard entropy change of reaction (HL) This video covers how to calculate the standard entropy change of reaction using absolute entropy values. You then subtract products minus reactants. The conversion of orthorhombic sulfur to monoclinic sulfur is endothermic, with H 0.401 kJ/mol at 1 atm. We can calculate the ∆S° system (which is the same as ∆S° rxn) by adding together the standard entropies for the products multiplied by their coefficients and then repeating that for the reactants. Elemental sulfur exists in two forms: an orthorhombic form (S ), which is stable below 95.3☌, and a monoclinic form (S ), which is stable above 95.3☌. For a spontaneous process: ∆S° universe = ∆S° system +∆S° surroundings > 0 For a process at equilibrium: ∆S° universe = ∆S° system +∆S° surroundings = 0 Let’s focus on the entropy of the system, a reaction that we are studying. The second law of thermodynamics states that the entropy of the universe increases in for a spontaneous process and remains unchanged when a system is at equilibrium. Entropy can be calculated quantitatively. In 9, the entropy was described qualitatively, we were able to determine if the process shown showed an increase or decrease in entropy. In definition, entropy is the measure of disorder of a system. calculate the absolute entropy for any substance at any temperature. EQUATION( S): ΔS° reaction = Σ∆S° products − Σ∆S° reactants N OTES : Entropy (∆□) can be described both qualitatively and quantitatively. To calculate the entropy change for reactions, we simply look at the entropy. The standard entropy is usually given the symbol (So). On the other hand, in general the heat capacity can be temperature-dependent. When the entropy value is calculated for one mole of the substance in its standard state, the resulting absolute entropy is called the standard entropy. By definition,, and so we can write: If the heat capacity is constant, we find that. ![]() 1 The entropy change for a process can be calculated from the absolute entropies of the species involved before and after the process occurs. We can rearrange this equation: Substituting : Since the pressure is constant, 0 and this expression simplifies so we can integrate. B Calculate the entropy change for a chemical or physical process based on the absolute entropies of the species involved in the process ESSENTIAL K NOWLEDGE : ENE- 4. 2 ABSOLUTE ENTROPY AND ENTROPY CHANGE ENDURING U NDERSTANDING: ENE- 4 Some chemical or physical processes cannot occur without intervention. ![]() Δ S° is positive, as expected for a combustion reaction in which one large hydrocarbon molecule is converted to many molecules of gaseous products. ![]()
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![]() Once you've done this, you can easily color the part you have separated. In this case, you can choose the shape closest to the area you want to slice and adjust it to fit on the piece you want to slice. Sometimes, the SVG designs you download from Free SVG Download may not be separated, which means you won't be able to color them separately. This will divide the SVG into different layers, which you can then move around and easily change the color of. You can do this by clicking the "Ungroup" button in the toolbar on the right. To edit the downloaded files, the first step is to ungroup the SVG file. Instant Download Svg, Png, Dxf, Eps Clip Art Files. AU11.35 (70 off) 100+ Paw TY Designs Svg Bundle Layered Item, Clipart, Cricut, Digital Vector Cut File. Inside the file, you'll find files in both SVG and PNG formats. 260+ Designs Bundle Layered Items, Layered Vector, instant download, layered svg files, svg for Cricut, 52+ UNIQUE DESIGN. You can extract the files inside using any zip extraction program of your choice. When you download our files, they will come in a. Be sure to check out our collection of free SVG designs today! How To Use: With our SVG cut files, you can create wonderful projects and handmade products such as t-shirts, masks, pillowcases, blankets, mugs, thermos, bags, invitation cards, vinyl designs, wall prints, party decorations, and much more. Please note that these files are for personal use only and cannot be sold. We have some awesome SVG designs available for you to use.
![]() ![]() You can include fixed text in your image, or the date and time. This program will decorate the images taken by your webcam, adding drawings, dynamic or static backgrounds, effects, lenses, masks, blur, hats, hair, etc. Integration with popular livestreaming platforms. Man圜am Application is a program that will let you add effects to your webcams output.Audio effects, such as voice changers and sound effects.Green screen support for custom backgrounds.Screen sharing and picture-in-picture display.Text and graphics can be added to the video feed.License and operating system information is based on latest version of the software. Operating systems Vista / Win10 / Win7 / Win8 / WinXP 1. Virtual backgrounds and a variety of effects and filters. File size 25.92 MB (Multiple video sources for easy switching.With its range of features and customization options, Man圜am is a must-have for content creators, remote workers, educators, and anyone else who wants to make their online presence more engaging and professional. Man圜am is a powerful tool for anyone looking to improve their video chatting or live streaming experience. It also integrates with streaming platforms like Twitch and YouTube, allowing users to easily enhance their streams with Man圜am's features. Man圜am is compatible with a variety of video conferencing platforms, including Zoom, Skype, and Google Meet. It’s easy to find and use these new features: Choose a blank color as your video by going to Sources and choosing Blank Image. This new version allows you to choose a blank color source, rotate your video source, zoom your video, set up a slideshow for images and more. This feature is especially useful for remote workers and video conferencing. Man圜am 2.3.21 is now available for download. Users can replace their actual background with an image or video, making it seem like they are in a different location. One of Man圜am's standout features is its ability to create virtual backgrounds. It also allows users to draw and write directly on their video streams, making it a useful tool for presentations and tutorials. Man圜am offers a wide range of effects and filters that users can apply to their videos, such as face masks, background blur, and text overlays. With Man圜am, users can add multiple video sources, including pre-recorded videos, screenshare, and images, to their video calls and recordings. Man圜am is a popular software that allows users to enhance their video calls, streams, and recordings with a variety of effects and tools. ![]() ![]() ![]() People might suppose this was in poor taste. Suppose there were groups of secularists at hospitals who went round the terminally ill and urged them to adopt atheism: 'Don't be a mug all your life. ![]() It will wake you up really fast to never stop believing. When you spend as much time as I do with wounded warriors and their families, and terminally ill kids and their families, you are humbled and powerfully inspired by their courage and positive energy to live your life to the absolute best you can everyday. There's probably no experience more alienating than fame, other than a terminal illness, where you actually find yourself in a situation that nobody around you can relate to. Enjoy life and challenge the illness that you have. with Switzerland, where assisted suicide is legal for patients suffering 'intolerable health problems.' - Arthur Caplan 4Įven if you have a terminal disease, you don't have to sit down and mope. Morally, we're more comfortable with a situation where you don't cause death, but you hasten it. With terminal illness, your fate is sealed. Many individuals see nothing undignified about choosing to end their lives at the time and manner of their choosing - and many view such a choice as the meaningful culmination of a good life. Desmond Tutu 5ĭepression and hopelessness are not the only reasons terminally ill patients wish to end their lives. I pray that politicians, lawmakers and religious leaders have the courage to support the choices terminally ill citizens make in departing Mother Earth with dignity and love. Tell them firmly, "I am not paid to listen to this drivel - you are a terminal fool!" Otherwise, they make you as crazy as they are. Burroughs 8ĭo not proffer sympathy to the mentally ill it is a bottomless pit. Just a month for each exposure, controlled of course, and a good heavy dose of excruciating pain. From acute infections to terminal cancer - and Kuru, the laughing sickness. ![]() ![]() Wouldn't it be great,as Scott Peck suggests, if all medical students had to undergo the symptoms and feeling of a spectrum of illnesses. We all just realized that I am terminally ill and I'm dying and I would just prefer to die with less pain and less suffering. You can do much more than you thought you could, including cure yourself of a "terminal illness". Stephen Hawking 19 When "i" is replaced by "we", even "illness" becomes "wellness".Īll suffering is caused by the illusion of separateness, which generates fear and self-hatred, which eventually causes illness. I think those who have a terminal illness and are in great pain should have the right to choose to end their own life, and those that help them should be free from prosecution. I did not fully understand the dread term 'terminal illness' until I saw Heathrow for myself. No one does! So be happy now, without reason-or you will never be at all. You don't have more than a few years left. Wake up! If you knew for certain you had a terminal illness-if you had little time left to live-you would waste precious little of it! Well, I'm telling you.you do have a terminal illness: It's called birth. Hopefully, these terminal illness quotes will keep you motivated not only during hard times but to expand your terminal illness knowledge! We've compiled this selection of inspirational terminal illness quotes. Following is our list of the best terminal illness quotes and sayings. ![]() ![]() ![]() Utility bills (causing you to pay your bills incredibly late).Family member’s ashes (this is quite a morbid one but it has happened in the past).Cash (yes, it isn’t wise to send paper money in the post but some people still do).Invoices (for services like building work, renovations, and more).Birthday presents sent from family members who live overseas.So, what might they take from your previous mailbox if you forget to complete the United States Postal Service’s change of address form? Let’s have a gander at some of the articles that we know have been swiped from people: However, when you dig down to the bare bones of the documents and packages that people have sent via mail, the effects of someone stealing them can be awful. Mailbox burglary is a real and devastating act to be a victim of (even though it may not seem like it at the moment). You Might Become a Victim of Mailbox Burglary (This Could Be Worse Than You Think) However, it is very likely that their actions will cause you (and even your family) some serious problems. But just remember that they may not be innately evil people. ![]() Generally, they tend to be charming, sweet, and friendly - this is a ruse to let your guard down. Of course, swiping your mail isn’t necessarily the only way they can take your information. Thieves believe that identity theft is a pretty risk-free way of getting their hands on some cash quickly. The main question remains though why do people steal identities? Truthfully, it all boils down to one thing: money. Having said this, some might take letters from loads of different people throughout a couple of weeks after carefully planning a zip code-wide scheme. They might grab a piece here and there over a long period of time until they have all the information they require. Typically, if someone is stealing your mail to take your identity, they are going to be smart about it. However, it can be so damaging that we felt we should give identify theft its own section. To be completely honest with you, this one pretty much ties in with our mailbox burglary point below. You Might Become a Victim of Identity Theft We don’t need to tell you how disastrous the consequences of this could be. It was unfortunate really just how many of these people were late paying their bills because they forgot to fill out a change of address form. ![]() While this was performed in the United Kingdom, it is clear that these issues related to the United States of America as well. But before we get into all of that, let’s take a look at the problems that can arise if you do not forward postal mail to the correct person (whether that be you or someone else.)Ī survey was conducted a few years ago on 2,000 homeowners relating to the problems they had when they forgot to change their mailing address. In order to do this however, you will need to realize the different reasons you would want to forward a letter to someone (or yourself). As part of that effort, today we will be discussing a very common question you have been asking us surrounding how to forward mail to another address. Luckily, most people won't need the premium forwarding service, as long as they update their address with any person or store they're expecting a package from as early as possible.Here at US Global Mail, it is our intention to make sure we address every single question you may have, when it comes to mail forwarding and mail scanning. That costs about $22 to enroll, and then another $23.90 each week the service is used. To get those packages forwarded to a new address, you'll need to sign up for “premium” forwarding service.
![]() ![]() Step 17: Save the changes and exit the window. Step 16: Click on “Choose a fit” and select “Fill.” Step 15: Browse to the folder where the animated wallpaper is located and select it. ![]() Step 14: Click on “Background” again and select “Picture.” ![]() Step 13: Exit the Desktop Icon Settings window and return to the Personalization window. Step 12: Navigate to the folder where the animated wallpaper is located, select it, and click on “OK.” Step 11: In the Desktop Icon Settings window, click on “Browse.” Step 10: Under “Themes,” click on “Desktop icon settings.” Step 9: Click on “Theme settings” under “Related Settings.” Step 8: Scroll down and click on “Themes.” Step 7: Right-click on the desktop and select “Personalize” again. Step 6: Once the app is installed, select the animated wallpaper you want and download it. Step 5: If you would like to set an animated wallpaper, you will need to download and install a third-party app such as Wallpaper Engine or RainWallpaper. You can also select the timing for the slideshow and choose an aspect ratio. Step 4: Here you can add folders to create a slideshow of your desired images. Step 3: Under the Background settings, click on the drop-down menu under “Background” and select “Slideshow.” Step 2: In the Personalization window, select “Background” from the left sidebar. Step 1: Right-click on the desktop and select “Personalize.” Here are the steps to set live wallpapers and animated desktop backgrounds in Windows 10: This feature allows users to personalize their desktop backgrounds with motion graphics and interactive visuals, making their workspace more appealing and engaging. In Windows 10, users can set live wallpapers and animated desktop backgrounds to give their desktops a new look and feel. ![]() ![]() ![]() The Northern California Megaregion comprises 164 cities (incorporated). Los Angeles, which has a population that’s quickly approaching 4 million as of 2017, is not just the largest city by population in the state but is also the second largest city by population in the entire nation. The number of cities in Northern California can change over time as new cities are incorporated, or existing ones may change their status. The map of California cities gives you a sense of just how expansive California is, from San Diego in the south to San Francisco in the middle to Crescent. The state of California has three cities that exceed population counts of over one million: Los Angeles, San Diego and San Jose. Yuba County How many cities are in Northern California? Table Of Contents: Map of Northern California List of Counties in Northern California Northern California Cities and Towns by Population Let me tell you about Northern California the way no one ever did Map of Northern California: First established in 1965, California City has grown to become home to more than 14,000 people. California City has one of the largest land areas of all cities in the United States at over 203 square miles. Plan your next adventure with our comprehensive guide. Perched on the edge of the Mojave Desert, California City, CA is a desert oasis and a great place to live. We have reviews of the best places to see in California City. ![]() ![]() Find what to do today, this weekend, or in January. Los Angeles, with a population at the 2020 United States Census of 3,898,747, is the most populous city in California and the second most populous in the United States, after New York City, on a land area of 468.67 square miles (1,213.8 km2), and is located in the southern region of the state. New York state’s Hudson valley area could get 2-4in of snow this weekend, CNN reported. Dive into the natural wonders and vibrant communities of North California. Things to Do in California City, California: See Tripadvisors 715 traveler reviews and photos of California City tourist attractions. Explore the Beauty of Northern California: Discover diverse Northern California cities, counties, and attractions. ![]() ![]() So while this card can be a great way to earn rewards on your shopping, you’re restricted as to how you can redeem them. These awards can only be used at BJ’s, though - either at checkout or to pay membership fees. When you’re ready to get that cash back, it comes in the form of electronic awards issued in $20 increments. Many BJ’s locations have their own gas stations as well, and cardmembers can enjoy an instant discount of 10 cents per gallon when using a BJ’s Perks Elite Mastercard to fuel up. The BJ’s Perks Elite Mastercard takes wholesale prices up a notch, offering cardmembers 5% back on purchases at BJ’s, 2% back on dining and gas purchases, and 1% back on everything else. Wholesale club prices are often hard to beat and make for great options for anyone looking to save while shopping. The best cards offered by Comenity Bank we recommend BJ’s Perks Elite Mastercard To give you a better idea of what you can expect from one of these store cards or credit cards, here are a couple of examples of some of the best cards Comenity offers. You'll typically need a higher credit score to be approved for a co-branded credit card, and while its APR might not be as high as a store card, the rate will vary from card to card. These credit cards can be used in store and anywhere else that brand of card is accepted. This type of card bears the name of both the retailer and the network it's on - Visa, Mastercard, American Express, or Discover. On the other hand, co-branded credit cards - or open-loop cards - give cardmembers more flexibility in how they spend. This can be costly if you don’t pay your balances in full each month. However, store cards also tend to have higher APRs (annual percentage rates) as well. They’re also generally easier to get approved for than regular credit cards. Many store cards come with perks like discounts, rewards programs, special financing options, and even birthday gifts. So, for instance, if you open a store card at Boscov’s, you can only use it at Boscov’s. Store cards can only be used to make purchases from a single company or retailer, such as a department store. Private-label credit cards - also known as closed-loop cards or store credit cards - are credit cards or credit lines issued by a bank on behalf of a store. What are private-label and co-branded credit cards, you may ask? Some of these retailers include stores such as J.Crew, New York & Company, Bed Bath & Beyond, Ikea, Overstock, and many more.Ĭomenity offers both store cards and credit cardsĬomenity Bank issues both private-label and co-branded credit cards for its retail partners. Considering that Comenity provides credit programs on behalf of so many retailers, you might already be a cardmember yourself. The parent company also oversees Alliance Data Retail Services, which is also a credit card company.Ĭurrently, more than 50 million cardmembers hold an account with Comenity Bank. ![]() The bank is a subsidiary of Bread Financial, a financial services company, which recently changed its name to Bread Savings. While it changed its name to Comenity Bank in 2012, it continues to provide the same credit cards and high-yield savings accounts to its customers. Those store cards the clerks always ask you if you’re interested in applying for? Those are private-label credit cards.Ĭomenity Bank was first formed as World Financial Network National Bank in 1989 with the goal of providing private-label credit card services to various retail establishments. If you’ve ever bought anything from a department store - which you probably have - you know exactly what I’m talking about. These financing solutions make their way to you as a consumer in the form of private-label and co-branded credit cards. Getting approved for a card from Comenity BankĬomenity Bank provides financing solutions to many popular brands around the world - more than 135 retail partners to be precise.The complete list of cards offered by Comenity Bank.The best cards offered by Comenity Bank we recommend.Comenity offers both store cards and credit cards. ![]() ![]() ![]() ![]() Not for consumer sale or use.ģM industrial and occupational products are intended, labeled, and packaged for sale to trained industrial and occupational customers for workplace use. In the end, these technologies help customers like you deliver competitive products to the market faster and more efficiently.įor industrial/occupational use only. The 3M Industrial Adhesives and Tapes Division applies the science of adhesion to deliver innovative solutions that improve the design and manufacturing processes of companies around the world. The unique acrylic chemistry is extremely durable and resistant to change over time, making this a long-lasting and powerful tape you can trust.īringing Better Ideas to the Surface through Science and Innovation Chemically resistant as well as UV and temperature stable, 3M™ VHB™ Tape can withstand the heat of Dubai to the cold of Canada. This versatile line of tapes can be used indoors or outdoors in a variety of applications, including window, door and sign assembly, electronics, construction and countless other industrial applications. In most cases, fastening with 3M™ VHB™ Tape is a quicker process than drilling, fastening, or using liquid adhesive. This tape enhances the appearance of finished goods by eliminating rivets and screws while providing immediate handling strength. This trusted and reliable tape offers a consistent bond, outstanding durability and excellent solvent and moisture resistance.ģM™ VHB™ Tape offers a durable bond in a way that mechanical fasteners can't. Skyscrapers, cell phones, electronic highway signs, refrigerators, architectural windows and more all rely on this specialty bonding tape for one or more steps in the assembly, mounting, fastening and sealing process. 3M™ VHB™ Tape is a proven alternative to screws, rivets, welds and other forms of mechanical fasteners. The result is a family of extraordinarily strong tapes that adhere to a broad range of substrates. These unique tapes combine conformability with a strong, permanent bond. Applications for this tape include bonding and sealing polycarbonate lens over LCD, signage and windows to post-painted control panels.ģM™ VHB™ Tapes were invented in 1980 as the first of their kind. It is specifically designed for good adhesion to high, medium and lower surface energy plastics and paints, metals and glass. The combination of strength, conformability and adhesion makes this family one of the most capable and well-rounded 3M™ VHB™ Tapes. The 5952 family of 3M™ VHB™ Tapes utilizes modified acrylic adhesive on both sides of a very conformable, adhesive foam core. Post up picks and let us see how it turns out.3M™ VHB™ Tape permanently adheres one substrate to another and spreads the stress load across the entire length of the joint Dream, Design, Deliver with the 5952 Family of 3M™ VHB™ Tapes This is just my 2 cents, your mileage may vary. That way you aren't working overhead the whole time. It'll be easier if you can take the shell off, remove the windows and then turn it upside down. Perhaps look at headliner material or speaker box carpet, as those materials stretch easily. If your shell is the same as mine, carpet with a backing will be tough to form into the area around the back lift gate and at each side of the front window behind the cab. Its good stuff.Īs for the carpet, try and find something that will stretch and conform to the contours of the shell. Mostly used for attaching laminate to counter tops. If you are dead set on carpet, I would recommend Weldwood Contact cement since you are attaching the carpet to the ceiling. Now it has a smooth shiny finish and the white works well in low light conditions. I rolled on two coats and filled a lot of the fiberglass mat in doing so. So I decided to sand and paint with Rustoleum gloss white. Looking at the angles and curves, it would be a tough job. I looked into the idea of putting on carpet when I removed all the windows to have it repainted. I have a Century shell as well with no carpet. ![]() ![]() ![]() Vibration sensors are useful for use with windows and doors, but less so for detecting movement in an open area. ![]() If you want to increase security inside your home by placing motion sensors indoors, think about where you’ll mount your new sensors. These models are durable, and can handle extreme temperatures and precipitation.Ī larger area is usually in question when monitoring the exterior of a home so consider motion sensors that have bigger detecting ranges. If you are looking to prevent people from coming close to your home in the first place, you may want to invest in outdoor motion sensors. What do you intend to do with the sensor? Are you concerned about potential break-ins? Or are you more focused on people coming close to the property at all? If a system includes indoor sensors, these will be deactivated while outdoor sensors will continue working. Many detectors offer users the option of enabling this function, which tells the motion sensor that someone is already in the home. This type of sensor is activated by the vibrations that occur due to movement. The double-step verification process reduces the chance of false alarms. Some motion sensors utilize a two-step process for detection that includes both passive infrared and microwave technologies. The biggest drawback to microwave motion sensors is that they’re prone to false alarms. Intrusion by a moving object alters these frequencies, triggering an alarm. The sensor monitors the frequency of the reflected waves. This type of motion sensor detects movement from a distance by using microwaves fill a target area. Infrared is useful for monitoring large areas, and is sensitive enough to detect movement. Passive Infrared sensors use body heat to detect movement and potential intruders. ![]() This is one of the most common types of motion sensors. Your needs will dictate which type is best for you and your unique situation. There are various types of motion sensors on the market. Some even mimic a dog to drive away intruders. Some motion sensors can make different noises when people approach. ![]() |
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